And it will be the most annoying thing in the world, especially for mac users. Downloading another application found on the internet to open these files will be an instant turn off from using the addon.
Using tar.gz (.tgz) or tar.bz2 approximates most if not all of the same savings compared to .zip and has the added bonus of requiring no additional software on Linux or Mac OS X. Just double-click or tar xzf JQuery.v19-1.4.2.tgz (to create, use tar czf JQuery.v19-1.4.2.tgz folder-name if I remember correctly).
In my experience, GZ is comparable to ZIP, BZ2 somewhat better like RAR, but on the whole they all pale in comparison to the LMZA/PPMd (if mainly text) routines used in 7z.
Meh. It's all moot, as if you use gzip in Apache to send the .zip files, you're probably sending less data than you think. http://httpd.apache.org/docs/2.2/mod/mod_deflate.html (Not necessarily supported by all browsers, can cause extra overhead, but still an improvement. Edit: Well, maybe not that much of an improvement on a .zip, but still...)
Anyway, here are the numbers from best to worst - bz2 fares quite well:
Of the above formats, what are best known? ZIP. So I'd suggest using .zip primarily, and if you want to make extra work, then also support alternative formats (.7z, .tgz, whatever people want to upload) but I wouldn't require something other than .zip, as "it just works" for all operating systems from Windows ME onwards, no downloads required.